Happily
enough, the essential fabrication steps for
many types of flexible circuits—etching the circuit
layers, adding a layer of metal for the wiring, and
etching that to shape—can all be accomplished with the
relatively cheap, and widely available, technologies
used to print ink on paper. In fact, technologists are
now working on several flexible-circuit manufacturing
processes based on printing on paper. One is a
modification of inkjet printing, the process at the
heart of countless desktop printers [see photo,
"Cut and
Print"]. Another adapts roll-to-roll
processing, a technique commonly used to print fabrics
and newspapers. A roll of unprocessed plastic is put
through a processing step and is rolled up again after
the step is completed—like movie film passing through a projector.
Tantalized by the prospect of a new,
multibillion-dollar market, inkjet-printing companies
like Dimatix, in Santa Clara, Calif., and Litrex Corp.,
in Pleasanton, Calif., are developing processes that
could replicate the basic steps of IC manufacturing—in
machines not much bigger than desktop printers. How big
is the commercial potential of an inkjet process for
making circuits? Big enough to have inspired Dimatix
recently to change its name from Spectra Inc., its
headquarters from Lebanon, N.H., and its focus from
printing posters to printing electronics.
In inkjet
printing, tiny nozzles squirt droplets of ink
onto a sheet of paper. There are two types of inkjet
printers—those that use heat from resistors to form
tiny bubbles to push the ink out of the nozzles and
those that use a piezoelectric material inside each
nozzle, which deforms when a voltage is applied. Under
voltage, the piezoelectric material vibrates, pushing
the ink out of the nozzle. These same mechanical
vibrations pull more ink into the nozzle to replace the
ink that was squirted out. The digital data for the
document tells the piezoelectric material where and when
to vibrate to get the drops in just the right places. In
the heat method, the data sends current through the
resistors to achieve the same result.
According to Dimatix scientists, only the
piezoelectric process is suitable for making plastic
electronic circuits, because the hot resistors used in
the other method would damage both the polymers that
make the transistors and the plastic substrates
themselves. However, Hewlett-Packard is developing a
process for printing circuits using the thermal process.
To print circuits instead of documents, Dimatix
researchers replace the ink with a liquid containing an
organic semiconductor or a metallic conductor. Today,
inkjet-compatible liquids are also available for
printing organic polymers to make the semiconducting
components, and for laying down silver to make the
connective wires. But at the moment no suitable liquid
has been found for printing amorphous silicon with inkjets.
As you might expect, the printhead that Dimatix
engineers developed for printing circuits is more
complicated than the ones in desktop inkjet printers.
There are more nozzles—over 100 on a circuit printer,
compared with 30 on a desktop machine. Adding to the
complexity, the direction in which each nozzle fires and
the amount of ink in each drop are individually
controlled—features not found on desktop printers.
These capabilities are needed to achieve the
resolution and precision required for useful circuits.
Today, the Dimatix jet heads can print lines and spaces
50 m wide with 5-m accuracy. Soon engineers expect to be
able to bring line widths down to less than 10 mm.
In the Philips
project, specialists at the Netherlands-based
giant are working with Dimatix jet heads to print
plastic organic-light-emitting-diode (OLED) displays for
cellphones and other applications. By spraying solutions
of red, blue, and green organic light-emitting material
onto the display substrate, they have produced displays
of up to 2 inches measured diagonally that are every bit
as crisp and bright as displays made on glass
substrates. Other researchers are using the inkjet
technique to apply the color filters for LCDs.
Litrex Corp., which makes inkjet printers using
Dimatix printheads, is also getting into circuit
printing. It has already built inkjet printers for
making flat-panel displays on both glass and plastic
substrates. Including printers installed in R&D
labs, Litrex has sold more than 50, mostly for making
OLED arrays.
For making circuits, the failure rate of the inkjet
nozzles must not be more than about a thousandth of the
1 percent or so allowed for printing documents. Litrex
developers have achieved this level of reliability by
including a high-speed camera in each printer that
visually inspects the drops from each nozzle. It can
capture images of single drops fired at a rate of up to
20 000 per second. The display substrate is loaded into
the printer only after the inspection shows that all
nozzles are firing correctly.
Litrex engineers are now testing a printer for large
2.4- by 2.4-meter substrates, now a standard size used
by display makers. Although it is technically possible
to build a single 2.4- by 2.4-meter display, most
manufacturers build six separate displays within that area.
One important advantage of the inkjet print process
over conventional techniques is that the jet process
puts the circuit material only where it is needed,
whereas the conventional process puts the material down
over the whole substrate and then etches most of it
away. But the fluids used to make electronics are
pricey—up to US $10 000 per liter. A 7-inch-diagonal
display printed conventionally might require a
milliliter of these fluids, costing about $10. But an
inkjet process would use only half a milliliter, saving
the manufacturer $5. Multiply this by millions of
displays, and it amounts to considerable savings.
At Motorola Inc., in Schaumburg, Ill., senior manager
Daniel Gamota and his colleagues are taking printed
electronics one step further. They are using
conventional printing presses—the same ones that make
posters and consumer product labels—to make circuits.
These presses typically use metallic, rubber, or plastic
cylinders 30 cm wide and 45 cm around, in which the
patterns to be printed are etched.
Gamota and his team rent time on such printers from
graphics arts companies and replace the standard
printing inks with an assortment of electrically
functional inks, which could be conducting,
semiconducting, or insulating and organic or inorganic.
So far they have produced more than 50 kilometers of
circuitry, mostly timing and control circuits that
switch at tens of hertz. These still-experimental
circuits are too slow, even for displays. But they are
fast enough to make electronically active labels for
consumer packaging. So, for example, a timing circuit
could switch on an indicator when a product reaches its
expiration date. Or a sensor could detect when a package
of food has spoiled.
Engineers are just starting to look into making
flexible electronics with the roll-to-roll process. By
eliminating the high-temperature, high-vacuum steps used
in conventional circuit manufacture, it holds the
promise of cutting the manufacturing cost by that magic
factor of 10 or better.
The Fraunhofer Institute for Reliability and
Microintegration, in Munich, Germany, has set up a
laboratory to develop roll-to-roll processing of
circuits on plastic. There, Karlheinz Bock and his group
have produced thin-film transistors from organic
semiconductors. They have measured individual
transistors that switch at speeds up to 2 kilohertz. The
first applications are likely to be low-tech and
inexpensive electronics for things like radio-frequency
identification tags and smart cards, though they can't
say when the process will be commercially viable.