There
is no Moore's Law for batteries, but that doesn't mean
you can't apply the same advances that have yielded increasingly
powerful computer chips to the problem of powering those
chips. This month, Marc Madou, a microelectromechanical
systems expert at the University of California, Irvine,
and his collaborators plan to demonstrate powerful chip-scale
batteries made using techniques borrowed largely from semiconductor
manufacturing. The inventors say the resulting microbatteries,
capable of delivering an intense burst of electricity or
a steady flow of relatively low current, would be suitable
for many applications, including sensors, cellphones, hearing
aids, and cardiac defibrillators. "You could use it for
all types of tiny electronic gadgets," Madou says.
Batteries
generate electricity through a chemical reaction in which
an electrolyte ferries ions between a pair of electrodes:
the positively charged anode and the negatively charged
cathode. The amount of current generated depends on how
much of the chemical reaction takes place—which depends
on both the surface area of the electrodes and the volume
of the battery's electrolyte. The more surface area there
is, the more current can be generated within the same volume.
That presents a fundamental challenge for small batteries,
which have neither expansive electrodes nor large volumes
of electrolyte.
Microbattery
designers typically try to work around limitations on current
by interleaving two stacks of thin, platelike electrodes.
That increases surface area and makes intense bursts of
current possible. But because of the low volume of the
electrolyte, the microbatteries still can't store much
energy.
Madou
and collaborator Chunlei Wang say they have improved current
flow even further and made room for more electrolyte by
designing a unique electrode made out of carbon that looks
like a bed of blunted nails [see photo, "Pillars of Power"]. The nails in this case
are 400 micrometers tall, with 20-µm gaps in between. Each
alternating row comprises anodes, followed by a row of cathodes. Because
the electrolyte can get in between the prongs, there is a huge increase
in surface area. And putting the anodes and cathodes in close proximity
means the ions in the electrolyte do not have to travel far. It is the
microscale equivalent of raising the speed limit on a highway and
widening it to 10 lanes. According to the researchers, a battery using such an electrode
can generate 78 percent more power than a stacked-plate microbattery of
the same volume.
To make
the carbon posts for the electrodes, the team used high-aspect-ratio
photolithography techniques that allowed them to build
tiny towers of plastic. They then heated the plastic spikes
to about 540 ºC until only the plastic's carbon remained.
Next Madou and his team attached leads to each point on
the "bed of nails," yielding a never-before-seen capability:
control over groups of electrodes that can be turned on
or off separately, allowing a single battery to produce
a wide range of voltages and currents.
The
team plans to present a completed carbon-pillar electrode
battery—whose energy storage they estimate will be
roughly 360 kiloamperes per cubic meter—this month
at the 206th meeting of the Electrochemical Society in
Honolulu. Compared with the smallest commercial batteries
such as those used in pacemakers, the 1-by-1-by-0.3-millimeter
microbattery they're developing should deliver three to
five times as much energy per unit volume.