Mataré's future
colleague Welker wasn't spared the
indignities of war, either. Allied bombs destroyed his
laboratory near Munich in October 1944. Early the
following year, this theoretical physicist, who during
the 1930s had worked on the quantum mechanics of
electrons in metals, began speculating about how to use
silicon and germanium to fabricate a solid-state
amplifier.
These two elements were widely regarded as metals
during the 1930s, but their apparent metallic behavior
was due largely to the high level of impurities in the
available samples. When foreign atoms of elements in the
fifth column of the periodic table—arsenic and
phosphorus, for example—become lodged in the
tetrahedral crystal structure of silicon or germanium,
four of their five outermost electrons form strong bonds
with nearby atoms, but the fifth is easily knocked away
and can thus transfer current through the crystal. The
much-higher-purity silicon and germanium that
researchers used to build radar systems during World War
II had far fewer of such current carriers and behaved
more like semiconductors than like metals.
In early 1945, Welker, who was mastering the art of
purifying germanium, recognized that the two
semiconductors could be used to make what we now call a
field-effect transistor. In fact, the device he had in
mind was strikingly similar to one that Shockley was to
suggest at Bell Labs a few months later.
In this scheme, an electric field from a metal plate
should penetrate into a thin surface layer of a
semiconductor strip beneath it, ripping electrons loose
from their parent atoms to serve as current carriers. A
voltage applied across the semiconductor strip would
induce a current through it. Crucially, a varying
voltage on the metal plate would modulate the current
through the strip. Thus, small input signals would
result in large output currents flowing through the
strip. Or so Welker figured.
But tests he performed in March 1945 revealed no such
amplification. In his logbook he recorded "only small
effects," orders of magnitude less than what was
predicted by Schottky's theory. Shockley, Brattain, and
their Bell Labs colleagues attempted similar tests that
very same spring, with similarly disappointing results.
The failures soon led Bardeen to postulate a novel
idea of "surface states"—that free electrons were
somehow huddling on the semiconductor surface, shielding
out the field. This conjecture, and Brattain's follow-up
experiments to determine the physical nature of the
surface states, led to their invention of the
point-contact transistor in December 1947—a month after
they discovered how to overcome the shielding.
After his failures, Welker returned to research on
germanium and resumed the theoretical studies of
superconductivity he had reluctantly abandoned during
the war. In 1946, British and French intelligence agents
interrogated him about his involvement in German radar.
They subsequently offered him an opportunity to work in
Paris in an R&D operation set up under the auspices
of a Westinghouse subsidiary, Compagnie des Freins et
Signaux Westinghouse. The immediate goal was to
manufacture germanium rectifiers for telecommunications
and military electronics.
While teaching in Aachen at his alma mater in 1946,
Mataré was also interviewed by agents. Fluent in French,
he received a similar offer. He eagerly agreed to join
the Paris effort, because doing research in devastated,
occupied Germany was almost impossible.
Then in their
mid-thirties, the two German physicists met
in Paris and began organizing their operation. They
found a vacant two-story stone house in the middle-class
suburb of Aulnay-sous-Bois, just northwest of the city.
In its basement, Welker set up his equipment to purify
and crystallize germanium. Mataré's testing and
measurements laboratory went on the ground floor, where
later that year a production line began fabricating what
soon amounted to thousands of rectifiers per month.
On the top floor the men kept offices and rooms where
they often stayed overnight—especially during that
frantic first year. Mataré wistfully remembers awakening
now and then to the soft trills of Welker playing his
violin in the adjoining room.
With the rectifiers finally in production by late
1947, Welker resumed his research on superconductivity,
while Mataré began to address the curious interference
effects he had seen in germanium duodiodes during the
war. When he put the two point contacts less than 100 mm
apart, he again occasionally could get one of them to
influence the other. With a positive voltage on one
point, in fact, he could modulate and even amplify the
electrical signal at the other! Mataré reckons he first
recognized this effect in early 1948 (perhaps a month or
two after Bardeen and Brattain's breakthrough at Bell
Labs). But it still happened only sporadically.
On a hunch, he asked Welker to fashion larger
germanium samples, from which they could cut slivers of
higher purity. Using this higher-grade material, Mataré
finally got consistent amplification in June 1948, six
months after Bardeen and Brattain. Encouraged by this
success, they phoned PTT Secretary Eugène Thomas and
invited him over for a demonstration. But Thomas was
apparently too busy—or perhaps not interested
enough—to come by.
About that time, Welker put aside his theoretical work
and tried to analyze what was going on just beneath the
shiny germanium surface of Mataré's odd contraption. In
an undated, handwritten document, now in the archives of
Munich's Deutsches Museum, Welker speculated that one
point—which he called the "électrode de
commande," or "control electrode"—was
inducing strong electric fields in the germanium just
beneath the other electrode, altering the material's
conductivity there.
But Mataré was not buying that explanation, which
followed the logic of Welker's unsuccessful 1945 attempt
at a semiconductor amplifier. If the phenomenon were
caused by an electric field, Mataré remembers thinking,
he should have witnessed a decrease in the current at
the second electrode, not the increase he observed on
his oscilloscope. According to this field-effect idea, a
positive potential on the control electrode would induce
negative charges in the germanium under the other
electrode, which should reinforce the current-blocking
effects of the barrier layer there.