PHOTO: John A. Rogers/University of Illinois at Urbana-Champaign
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Plastic power: Ring oscillators [left] and inverter circuits
[middle and right] made of silicon ribbons
printed on plastic.
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Silicon circuits that bend and stretch recently took
an important step away from the world of science-fiction
novels and Hollywood movies toward the real world of
medical devices and media players.
A team of researchers at the University of Illinois at
Urbana-Champaign (UIUC) says it has printed silicon
circuits onto plastic in the form of the same CMOS
circuits that dominate digital logic today. The
breakthrough brings researchers closer to printing
circuits on plastic that approach the performance and
reliability of silicon chips.
The team, led by materials science and chemistry
professor John A. Rogers, had earlier shown that they
could form circuits by transferring thin ribbons of
silicon onto glue-coated plastic using a patterned
rubber stamp. But the resulting devices used only
n-type
silicon, whereas CMOS logic has both n-type and p‑type. CMOS circuits
are generally more power-efficient, because current
should flow through them only when their bits are
flipping. In any portable electronic device, that means
longer battery life. But in the case of plastic
electronics, CMOS is even more important, because it
reduces the amount of heat produced—which, left
unchecked, could melt the plastic.
Rogers’s research, which was reported in January in
IEEE Electron
Device Letters, also showed that printed
plastic circuits can reach speeds matching those of
silicon chips. Rogers says his group has built silicon
circuits on plastic that switch at about 500 megahertz,
five times as fast as the clock in a 1995 Pentium
microprocessor. “And there’s no fundamental reason you
couldn’t go much higher,” he says.
The speed of these circuits greatly outstrips those
made using organic semiconductors, a key competitor in
the plastic electronics race. The main problem of
organics is inherently low charge-carrier mobility, the
metric describing the speed at which charges move
through a material. The best organics have mobilities of
about 1 square centimeter per volt second versus 85
cm2/Vs for Rogers’s CMOS
circuits.
The UIUC group’s technology also competes with
plastic circuits made from semiconductor nanowires,
such as those under development at Palo Alto,
Calif.–based Nanosys. Instead of etching off ribbons of
semiconductor from a wafer as the Illinois group does,
Nanosys and its partners chemically synthesize silicon
nanowires by means of vapor deposition.
The UIUC and Nanosys approaches “are similar
conceptually in that they take advantage of the fact
that single-crystal silicon is a good material for
charge transport compared with, say, organics,” says
Rogers. “And they both use silicon structures small
enough so that they are flexible and can be integrated
with plastic.” But Rogers is convinced that making your
own silicon when high-quality wafers are commercially
available adds an unnecessary complication to the
manufacturing process. Citing confidentiality
agreements with Nanosys’s commercial partners, the
company’s cofounder and vice president of business
development, Stephen Empedocles, declined to make direct
comparisons between the Nanosys and UIUC approaches.
Rogers’s technology is under development at Semprius,
a start‑up based in Durham, N.C., of which he is
cofounder. Besides refining the manufacturing process,
Semprius is working on making silicon-based
electronics that are not only bendable but
stretchable. That involves making the silicon thin
and then structuring “the material into a wavy shape so
it becomes like the bellows on an accordion,” says
Rogers. One application the company is investigating
is putting the stretchy circuits on spheres for
electronic eye–type imaging systems.