Illustration: Bryan Christie Design
|
You’re in a strange airport, your laptop’s running low
on power, there’s no wall socket, and your half-done
report must get done today or you’re toast. You gape in
horror as your screen fades to gray. The last thing you
see before it winks out is the depleted-battery icon.
That’s the nightmare scenario sketched by the
proponents of fuel-cell rechargers, and here’s the happy
ending they offer in its place: you smile as you pull a
fuel cartridge the size of a disposable lighter from a
flap in your briefcase and swap it for the laptop’s
depleted cartridge. The screen brightens, you hammer out
that report, and nobody gets hurt.
So why haven’t fuel cells already shouldered
batteries aside? Because fuel cells suck. Suck fuel,
that is.
And consumers have shown little interest in carrying
fuel around with them. People are set in their ways,
which helps explain why QWERTY keyboards, pocket
watches, and the Windows operating system are still with
us. A product can break through such habits only if it
offers obvious and overwhelming advantages, and so far
fuel cells have done so only in tiny niches of the market.
What do we mean by overwhelming? Well, instead of the
5 or 6 hours you get on a good day out of your laptop
battery, you could get several days of continuous
use, at least in theory, with an advanced fuel cell.
News cameramen are big fans of rechargers, because
they have to be absolutely sure they’ll have power out
in the field, says Jeff Shepard, publisher at the
Darnell Group, an industry consultancy in Corona,
Calif., that has studied the fuel-cell market. “But you
and I wouldn’t care,” he adds. “No way I’d pay for an
extra fuel cell.”
Other gotta-have-’em users include the military,
which wants soldiers to be able to lug all the power
they will need for days on end. But the military needs
something bigger than a mere laptop recharger, says
Thomas Reitz, a chemical engineer at Wright-Patterson
Air Force Base, in Ohio. “With a radio you’re normally
just listening, at 25 watts, but if you suddenly need to
transmit, you’d need 150 or more,” he says. “Because a
fuel cell designed to that spec would be too large for
its purpose, we design it for 30 W and use the extra 5 W
to charge a battery.”
Thirty watts is far more than you can wring from a
portable proton exchange membrane (PEM) fuel cell, the
kind that has been around for decades. The military is
therefore looking into a more powerful design that uses
a solid-oxide ceramic as the electrode. Such cells
derive their high performance from an operating
temperature that ranges from 600 to 1000 ºC. It’s not a
big problem for the military, because the cell comes in
a relatively large and well-insulated pack. And let’s
face it, if you’re going into combat, you’ve got other
things to worry about besides stray heat from your power
pack.
But shrinking the design down and applying it to
consumer applications is a decidedly courageous move.
Few companies are working on such products, and just one
has decided to make a commercial go of it: Lilliputian
Systems, a Wilmington, Mass., start-up.
“Consumer electronics need to use high-energy fuel,
to process it efficiently, and to keep it small, and
that really leads you to solid oxide,” says Ken Lazarus,
the company’s chief executive. “Also, it’s much less
vulnerable [than the PEM design] to impurities that
might ‘poison’ a catalyst, and to moisture. At high
temperatures, contaminants in the fuel tend to just burn up.”
Butane, the fuel in question, packs about 70 percent
more energy per gram than the methanol that is commonly
used in PEM cells. Butane is already packaged in
disposable plastic cigarette lighters, and several
international aviation agencies, including the U.S.
Federal Aviation Administration, have recently allowed
fuel-based rechargers aboard planes. It may, however, be
hard to impress that point of law on the nervous,
submachine-gun-toting guards at some of the world’s more
remote airports—precisely the kind of places where you
might want a reliable, long-duration power source, in
other words.
The heat, though, is what critics always mention
first. “I don’t want 600 degrees sitting on my lap,”
says Shepard.
“It sounds like a bad problem, especially in a
product like a laptop, which already has a problem
dissipating heat,” says Daniel Rosen, executive chairman
of Neah Power Systems, in Bothell, Wash., which makes a
PEM fuel cell.
Lazarus dismisses their concerns, saying that his
product grew out of an MIT project that was expressly
aimed at building high-temperature reactors on silicon
substrates. The solid-oxide electrode is laid down on
the silicon and enveloped in a bubble that thermally
insulates the active region in a vacuum. “Think of the
filament of a lightbulb, burning at 2500 ºC, but in a
vacuum package,” he says. “The outside of our cell is
basically at room temperature.”
Other experts who specialize in solid-oxide fuel
cells agreed that such vacuum packing seemed doable.
What they wanted to know was how the electrodes could
last through many heating and cooling cycles, which
would cause the ceramic and silicon layers to expand and
contract at different rates. What keeps the package from
coming apart at the seams?
Lazarus says the company has several ways of keeping
things together. First, the cell’s active area is small,
so that the varying expansion rates produce only small
absolute differences in size. Second, the ceramic
electrode is precracked, as it were, so that it harbors
the kind of expansion joints that keep a concrete
sidewalk from crumbling. The trick is to make the tiles
the right size.
“Think of a dry lake bed,” he says. “It’s cracked,
but only to a certain size—it doesn’t turn to dust. If a
device is smaller than this critical size, it won’t
crack.”
Lazarus didn’t spell out how his company keeps the
seal intact. Alex Ignatiev, the director of the Center
for Advanced Materials at the University of Houston,
suggests that the company has built a kind of sandwich.
“You can have silicon expanding at one rate, put a layer
on top that doesn’t expand quite so much, then another
that expands a little less, then finally the ceramic
layer,” he says. Yet even a sandwich can go through only
so many expansion cycles before it falls apart, Ignatiev
points out.
“They don’t say what the lifetime is,” he notes.
“Lifetime is defined by temperature, materials, and the
time of heating and cooling, and eventually you will get
cracks, like in highway bridges, where the concrete
doesn’t expand as much as the steel. The cracks become
defect points, propagating bigger cracks.”
But for the moment, let’s assume that Lilliputian
Systems’ cell can do everything the company says and
last as long as the laptops (and, later, cellphones) it
is meant to power. Even then, the company must somehow
solve the marketing problems that have dogged
methanol-fueled rechargers.
Can everyday users be trained to carry fuel around?
To stock up on cartridges of it and keep them in their
desk drawers, briefcases, and glove compartments? Will
retail outlets in out-of-the-way places stock them? Will
that machine-gun-toting airport guard learn to wave
little vessels of butane onto passenger aircraft while
turning away 3.1 ounces of shampoo? Most important: will
battery makers sit idly by, watching this upstart eat
their lunch?
We think not. Miniature solid-oxide fuel cells may
find niche applications, but few people will use them
anytime soon.